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Analytical Quality Control in Laboratories in Senegal and Mali - Analysis of Organic Contaminants and Trace Metals

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Analytical Quality Control in Laboratories in Senegal and Mali - Analysis of Organic Contaminants and Trace Metals In this report the results of organochlorine pesticide analysis in 20 sediment samples are being discussed. These samples were analysed by the Vrije Universiteit Amsterdam and compared with the results obtained in the same samples (10) in Senegal and (10) in Mali. In addition, trace metal concentrations were analysed by Eurofins Omegam, The Netherlands, in contract for the Vrije Universiteit Amsterdam. The results show that both laboratories (Senegal and Mali) still encounter a number of barriers. One essential issue is the inability to order analytical standards when they are needed. The ordering process takes an awful lot of time, up to half a year or more. Delivery times are long, and customs can hold packages for a long time as well. Costs are also an issue as these analytical standards are quite expensive. Therefore, the laboratories often order cheaper technical standards but those are not suitable. The same is true for certified reference materials and for consumables, especially expensive consumables such as GC columns. In addition, the basic knowledge of the staff is not as good as it should be. One employee in the Mali laboratory had been on training in Europe, which made the overall impression of that laboratory better. Suggestions are given for improvement. Metal concentrations were analysed by the Senegal and Mali laboratories and compared with data from the reference laboratory. The quality of the data in both laboratories is not much better than that of the OCP analyses. As regards the environmental quality, the OCP levels do not pose an environmental or human health risk. Nickel and chromium are somewhat elevated and may need extra attention regarding human health risks.

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Emerging contaminants in water: Regulation in Mexico, precautionary principle and comparative perspective

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This paper analyzes the status of legal regulation of emerging contaminants in water sources in Mexico. To this end, its relevance is debated in the context of the constitutional obligations assumed regarding the human right to water and sanitation (HRWS). The international instruments are reviewed and a brief general balance is prepared that allows us to reflect on the legal vacuum of this topic in Mexico. Emerging contaminants are shown to be substances of diverse origin and chemical nature, the presence of which in the environment is not considered significant due to their distribution and concentration, so they go unnoticed. However, due to the increase in their detection, the potential ecological impact and the risks they pose to human health, they have received recent attention in academic analysis, official studies and water quality policies. It is proposed, from the perspective of comparative law and under the precautionary principle approach, a scheme of national normative regulation, for that purpose, a comparative analysis is carried out with the Chilean and European legal frameworks. It is concluded that the absence of devices that regulate emerging contaminants hinders compliance with HRWS, especially that which refers to two central aspects: adequate sanitation and the supply of quality water for domestic consumption.

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